Recent Publications

Wendlandt, H. C.; Utley, J. A.; Lee, B. J.; Ho, T. D.; Hull, K. L. “A General Platform for Copper-Catalyzed Atom Transfer Radical Addition with Electron-Deficient Olefins,” Org. Lett. 2025, 27 (1), 241–245. doi:10.1021/acs.orglett.4c04260.

Gay, B. L.; Prendeville, L. A.; Wang, Y. N.; Hull, K. L. “Base-Free Borylation of Aryl Halides Enabled by Zn-Promoted Halide Abstraction,” Org. Lett. 2024, 26 (49), 10481–10486. doi:10.1021/acs.orglett.4c03821.

Lee, S.; Yu, J. D.; Monterde, A. L.; Tung, S. E.; Wang, Y. N.; Gay, B. L.; Hull, K. L. “Chemoselective Cu-Catalyzed Cross-Nucleophile Alkylarylation of Alkenes,” ACS Catal. 2024, 14 (18), 14242–14250. doi:10.1021/acscatal.4c03955.

Ho, T. D.; Lee, B. J.; Buchanan, T. L.; Heikes, M. E.; Steinert, R. M.; Milem, E. G.; Goralski, S. T.; Wang, Y.-N.; Lee, S.; Lynch, V. M.; Rose, M. J.; Mitchell-Koch, K. R.; Hull, K. L. “Cu-Catalyzed Three-Component Alkene Carboamination: Mechanistic Insights and Rational Design to Overcome Limitations,” J. Am. Chem. Soc. 2024, 146 (36), 25176–25189. doi:10.1021/jacs.4c08945.

Popov, A. G.; Viviani, V. R.; Skumial, P.; Jefferson, T. L.; Salman, S. G.; Baxter, H. H.; Hull, K. L. “Copper-Catalyzed Three-Component 1,5-Carboamination of Vinylcyclopropanes,” Org. Lett. 2024, 26 (22), 4621–4625.

 

Ho, A. T.; Vanable, E. P.; San Miguel, C.; Hull, K. L. “Iridium-catalysed hydroamination of internal homoallylic amines,” Chem. Commun. 2024, 60, 1615–1618.

Wendlandt, H. C.; Trammel, G. L., Kohler, D. G.; Utley, J. A.; Nicely, A. M.; Popov, A. G.; Hull, K. L. “Copper-Catalyzed Three-Component Carboiminolactonization of Electron-Deficient Olefins,” J. Org. Chem. 2024, 89 (3), 2024–2031.

Ho, T. D.; Lee, B. J.; Tan, C.; Utley, J. A.; Ngo, N. Q.; Hull, K. L. “Efficient Synthesis of α-Haloboronic Esters via Cu-Catalyzed Atom Transfer Radical Addition,” J. Am. Chem. Soc. 2023, 145 (50), 27230–27235.

Gay, B. L.; Wang, Y. N.; Bhatt, S.; Tarasewicz, A.; Cooke, D. J.; Milem, E. G.; Zhang, B.; Gary, J. B.; Neidig, M. L.; Hull, K. L. “Palladium and Iron Cocatalyzed Aerobic Alkene Aminoboration,” J. Am. Chem. Soc. 2023, 145 (34), 18939–18947.

Nicely, A. M.; Popov, A. G.; Wendlandt, H. C.; Trammel, G. L.; Kohler, D. G.; Hull, K. L. “Cu-Catalyzed Three-Component Carboamination of Electron Deficient Olefins,” Org. Lett. 2023, 25 (28), 5302–5307.

Bhatt, S.; Wang, Y. N.; Pham, H. T. P.; Hull, K. L. “Palladium-Catalyzed Oxidative Amination of α-Olefins with Indoles,” Org. Lett. 2022, 24 (31), 5746–5750.

Lee, B. J.; Ickes, A. R.; Gupta, A. K.; Ensign, S. C.; Ho, T. D.; Tarasewicz, A.; Vanable, E. P.; Kortman, G. D.; Hull, K. L. “Synthesis of Unsymmetrical Vicinal Diamines via Directed Hydroamination,” Org. Lett. 2022, 24 (30), 5513–5518.

Ho, A. T.; Ensign, S. C.; Vanable, E. P.; Portillo, D.; Humke, J. N.; Kortman, G. D.; Hull, K. L. “Rhodium-/Iridium-Catalyzed Hydroamination for the Synthesis of 1,2-, 1,3-, or 1,4-Diamines,” ACS Catal. 2022, 12 (14), 8331–8340.

Buchanan, T. L.; Gockel, S. N.; Veatch, A. M.; Wang, Y. N.; Hull, K. L. “Copper-Catalyzed Three-Component Alkene Carbofunctionalization: C-N, C-O, and C-C Bond Formation from a Single Reaction Platform,” Org. Lett. 2021, 23 (12), 4538–4542.

Gockel, S. N.; Lee, S.; Gay, B. L.; and Hull, K. L. “Oxidative Three-Componenet Carboamination of Vinylarenes with Alkylboronic Acids”, ACS Catal., 2021, 11, 5166–5171.

Qi, X.; Kohler, D. G.; Hull, K. L.; and Liu, P. “Energy Decomposition Analyses Reveal the Origins of Catalyst and Nucleophile Effects on Regioselectivity in Nucleopalladation of Alkenes”, J. Am. Chem. Soc. 2019, 141, 11892.

Vanable, E. P.; Kennemur, J. L.; Joice, L. A.; Ruck, R. T.; Shultz, D. M.; Hull, K. L. “Asymmetric Hydroamination of Allyl Amines,” J. Am. Chem. Soc. 2019, 141, 739.

Wu, Z.; Laffoon, J. D.; Hull, K. L. “Asymmetric Synthesis of γ-Branched Amines via Rhodium-Catalyzed Reductive Amination,” Nat. Commun. 2018, 9, 1185.

Gockel, S. N.; Buchanan, T. L.; Hull, K. L. “Cu-Catalyzed Three-Component Carboamination of Alkenes,” J. Am. Chem. Soc. 2018, 140, 58–61.

Kohler, D. G.; Gockel, S. N.; Kennemur, J. L.; Waller, P. L.; Hull, K. L. “Anti-Markovnikov Selective Pd-Catalyzed Oxidative Amination,” Nat. Chem. 2018, 10, 333–340.

Kortman, G. D.; Hull, K. L. “Copper-Catalyzed Hydroarylation of Internal Alkynes: Highly Regio- and Diastereoselective Synthesis of 1,1-Diaryl, Trisubstituted Olefins” ACS Catal. 2017, 7, 6220–6224.

Wu, Z.; Laffoon, J. D.; Nguyen, T. T.; McAlpin, J. D.; Hull, K. L. “Rhodium-catalyzed Asymmetric Synthesis of β-Branched Amides,” Angew. Chem. Int. Ed. 2017, 56, 1371–1375.

Buchanan, T. L.; Hull, K. L. “Illuminating Amination,” Science 2017, 355, 690–691.

Nguyen, T. T.; Hull, K. L. “Rhodium-Catalyzed Oxidative Amidation of Sterically Hindered Aldehydes and Alcohols,” ACS Catal. 2016, 6, 8214–8218.

Kennemur, J. L.; Kortman, G. D.; Hull, K. L. “Rhodium-Catalyzed Regiodivergent Hydrothiolation of Allyl Amines and Imines,” J. Am. Chem. Soc. 2016, 138, 11914–11919 .

Nguyen, T. T.; Kortman, G. D.; Hull, K. L. “Synthesis, Cycloaddition, and Cycloreversion Reactions of Mononuclear Titanocene-oxo Complexes,” Organometallics 2016, 35, 1713–1725.

Wu, Z.; Hull, K. L. “Rhodium-catalyzed oxidative amidation of allylic alcohols and aldehydes: effective conversion of amines and anilines into amides,” Chem. Sci. 2016, 7, 969–975.

Ensign, S. C.; Vanable, E. P.; Kortman, G. D.; Weir, L. J.; Hull, K. L. “Anti-Markovnikov Hydroamination of Homoallylic Amines,” J. Am. Chem. Soc. 2015, 137, 13748–13751.

Nguyen, T. T.; Bertke, J. A.; Gray, D. L.; Hull, K. L. “Facile C-H, C-F, C-Cl, and C-C Activation by Oxatitanacyclobutene Complexes,” Organometallics 2015, 34, 4190–4193.

Gockel, S. N.; Hull, K. L. “Chloroform as a Carbon Monoxide Precursor: In or Ex Situ Generation of CO for Pd-Catalyzed Aminocarbonylations,” Org. Lett. 2015, 17, 3236–3239.

Gupta, A. K.; Hull, K. L. “Synthesis of 1,2-Diamines via Hydroamination Reactions,” Synlett 2015, 26, 1779–1784.

Kortman, G. D.; Orr, M. J.; Hull, K. L. “Synthesis and Reactivity of Dioxazirconacyclohexenes: Development of a Zirconium-Oxo-Mediated Alkyne-Aldehyde Coupling Reaction,” Organometallics 2015, 34, 1013–1016.

Ickes, A. R.; Ensign, S. C.; Gupta, A. K.; Hull, K. L. “Regio- and Chemoselective Intermolecular Hydroamination of Allyl Imines for the Synthesis of 1,2-Diamines,” J. Am. Chem. Soc. 2014, 136, 11256–11259.